When writing a fully balanced chemical equation, it is assumed that all of the reactants will be converted into products, thus giving a yield of 100%. This is rarely the case as:
The percentage yield can be calculated by:
$$ \text{yield} = \frac {\text{actual product, mol}}{\text{theoretical product, mol}} \times 100 $$
A student is preparing some ethanoic acid, $CH_{3}COOH$ by heating ethanol, $C_{2}H_{5}OH$, with an oxidising agent. The reaction is shown below:
$$ C_{2}H_{5}OH + 2[O] \rightarrow CH_{3}COOH + H_{2}O$$
The student reacted 9.20g of ethanol with an excess of sulphuric acid and potassium dichromate. they obtained 4.35g of ethanoic acid. What is the percentage yield of ethanoic acid?
A reaction often produces by-products in addition to the desired product. These by-products are often considered as waste and are disposed of. This is costly and has environmental impacts. Atom economy not olny considers the desired product but also the by-products. The equation for atom economy is:
$$ \text{atom economy} = \frac {\text{Mr of desired product}}{\text{Sum of Mr of all products}} \times 100 $$
By using processes with a higher atom economy, companies can reduce the waste produced. The type of reaction is a major factor in achieving a higher atom economy:
To improve the atom economy, a use must be found for the by-products. In industry, this is sometimes done by selling off by products.
Methanol can be prepared by reacting potassium hydroxide with chloromethane. Calculate the atom economy for this reaction.
$$ CH_{3}Cl + KOH \rightarrow CH_{3}OH + KCl \\ \\
\eqalign{
\text{Mr of desired product } CH_{3}OH &= 12 + (4 \times 1) + 16 \\
&= 32} \\
\eqalign{
\text{Mr of all products } &= 32 + 74.6 \\
&= 106.6} \\ \\
\eqalign{
\text{atom economy} &= \frac {\text{Mr of desired product}} {\text{Sum of Mr of all products}} \times 100 \\
&= \frac {32}{106.6} \times 100 \\
&= 30.02\%}
$$